I can't remember how many times I've been asked about end user training for SharePoint from organizations and admins.  There have been some good books and trainers around, but now the Office guys have put together some self-serve training for users. 

Grab it up here - http://office.microsoft.com/en-us/sharepointserver/HA102488011033.aspx

Training topics included

Collaboration

• Finding your way around a team site
• Understanding permissions
• Customizing a team site
• Linking calendars to Outlook
• Adding Web Parts
• Collaborating in libraries, lists, and workspaces
• Using blogs and wikis to share information

Enterprise Content Management

• Document management
• Protecting files
• Using workflows
• Records management
• Creating and publishing Web pages
• Improving compliance and support litigation discovery

Search

• Finding files, Web sites, information, and people

Portals and personalization

• My Sites
• Targeting content to specific audiences
• Managing access to your My Site

Business processes and forms

• Streamlining business processes with forms and workflow
• Gathering information with browser-compatible forms
• Designing custom workflows using SharePoint Designer

Business intelligence

• Sharing Excel workbooks as interactive reports
• Working with a Report Center site
• Using dashboards to drive decisions
• Understanding Filter Web Parts
• Integrating external data